Let’s face it, Chemistry can be a pain. Named reactions, mechanisms, compounds, resonance, the periodic table... gah! But that doesn’t mean it can’t be fun. The world is filled with crazy crap to learn and laugh about.

Hey, I’m Amogh Sood and this is The Blank Notebook, the Chemistry blog for high school students by a high school student. Whenever that NCERT textbook seems too scary to look at, drop by and see what we’re talking about. Hopefully my homemade comic strips will keep you interested. Come for the laughs, stay for the learning.

Just remember: A Blank Notebook a day keeps blank answer sheets away!

Maintained by Amogh Sood (also know as the The Passive Observer). Plagiarism is not cool, please take due permission if you intend to use some of my work.

Saturday, 6 April 2013

What The Fact...Fire!

What is Fire?

"Fire" is rapid oxidation of a substance in an exothermic process (combustion). A fire is started when a combustible material combines with sufficient quantities of an oxidizer ( such as oxygen or an oxygen rich compound. Non-oxygen oxidizers can replace oxygen).



The flame is the visible portion of the fire and comprises excited gas/fuel/unburnt particulate matter.

Energy released by the exothermic process is sufficient to excite the electrons in some of constituent atoms and transient intermediates comprising the flame. The excited electrons then fall back to the ground state releasing the absorbed energy as visible light.

Quick Tip: Okay, picture this, an electron walks into a party and drinks a lot. (The brewskis equal energy.)
Now he gets super hammered (i.e goes to a higher energy state) and then later throws up (i.e returns to the ground state). Now if we assume that the electron drank nothing but beer and if we ignore the trace amounts of gastric juice, saliva, and his lunch in his vomit, we can safely say that beer (energy) he egested is equal to the beer (energy) he ingested.



The color of the flame depends primarily on two factors: blackbody radiation and spectral band emission

Typically, in case of complete combustion the excited gas molecules emit pale blue light due to energy transitions (explained above). This is the reason why most gas flames are blue in color.

However, in case of incomplete combustion, the yellow/orange/red color of the flame is due to incandescence of soot particles which glow red hot.

As you may already know that all bodies with temperature above absolute zero (0 K)  emit certain electromagnetic radiation corresponding to their temperature.

(Humans emit electromagnetic radiation too, so does your cat and your dog and everything you see around you. The reason we aren't suffused with an incandescent glow is because we are too "Cool" to radiate visible light, rather, we emit infrared radiation..oh yeah!)

Temperature as you know is a measure of the motion of particles constituting matter, and since some of the particles constituting any object will carry charge their movement will lead to the release of electromagnetic radiation i.e light.

The Shape of the Flame

The familiar teardrop shape of a candle flame, here on earth is due to buoyant convection of gas molecules.
The rising hot gases also carry unburnt soot particles to the top of the flame, which make the flame appear yellow.

However, in micro-gravity  convection currents are absent and the flame appears somewhat spherical, spreading out in all directions. The flame also appears blue because the soot particles settle down, instead of  being carried to the top of the flame by convection currents.



Starting A Fire

The match head of a modern "safety match" is typically composed of  potassium chlorate, with a little sulfur and some form of siliceous filler and glue. Some heads contain antimony(III) sulfide to make them burn more vigorously. Safety matches ignite due to the extreme reactivity of phosphorus with the potassium chlorate in the match head.

The main reactant on the striking surface on modern matchboxes is red phosphorous. Safety matches ignite due to the reaction between potassium chlorate and phosphorous. The striking surface also consists of some  amount of abrasive material like powdered glass.

DIY Strike Anywhere Matches: Strike anywhere matches are hard to come by (especially here in India) so here's how you can make some at home.

What you need: a) Sand paper
                         b) Several matchboxes
                         c) Matchsticks

Using the sandpaper, sand off the red phosphorous from the striking surface of a couple of matchboxes ( you may need about 5-10)

Collect the red phosphorous in a container and mix it with some water. Dip the match heads in the mixture and coat them liberally, after which you can leave them out to dry. Once the water has evaporated, test the matches by striking against any rough surface.


Starting a fire without a match

Combustion, ultimately, is a chemical reaction. Here's a nifty way to start a fire you using chemistry.

Add glycerin to some potassium permanganete, give it about 30 seconds to initiate and Voila, Fire!

What happens here is the glycerin is oxidized extensively by the potassium permanganete and the resulting reaction is highly exothermic and produces a flame.


___________________________

That's all Folks!

The Passive Observer Out!


Confused? Reduction-Oxidation..dafuq?

Do some quick reading

Redox Reactions







The Periodic Table

The periodic table is a system in which elements are organized on the basis of their atomic numbers, electron configurations, and recurring chemical properties. 

Several scientists, Newland, Doberneir, Meyer, Mendeleev..among others, tried to come up with such a system. 

Mendeleev came up with the first widely recognized periodic table in which he arranged elements in horizontal rows and vertical columns and grouped elements with similar chemical properties together.

As the story goes, the idea for his periodic table struck Mendeleev when he was playing with himself (playing cards, you perv..a game called solitaire or patience).


click to enlarge


Mendeleev concluded that chemical properties of an element are a periodic function of their atomic masses. He also predicted the existence of germanium, gallium and scandium. 

Sure there were a few issues with his work.

Problems:


1. Mendeleev couldn't account for the isotopes of an element. (isotopes of an element have the same atomic number but different atomic masses.). For example, an isotope of carbon is 14C. This would have to be accommodated along with nitrogen. But 14C shows properties similar to those of carbon (12C). 

2. In order to ensure that elements in a column have similar chemical properties, Mendeleev was forced, in a few cases, to put an element of slightly higher atomic weight ahead of one of slightly lower atomic weight. Thus, tellurium (atomic weight 127.6) had to be put ahead of iodine  (atomic weight 126.9) in order to group Iodine with other halogens on the basis of similar chemical properties.

But his system worked well (for the most part) and he had an awesome beard, and he has a brand of  vodka named after him..so he gets the The Passive Observer seal of approval.


The modern periodic law differs from Mendeleev's and states that chemical properties of an element are periodic functions of their atomic number.

In the modern periodic table (pictured below) the rows are called "periods" and the columns are called "groups"


click to enlarge

Groups 1 and 2 (alkali metals and alkaline earth metals) constitute the s-block with their valence electrons occupying the s-orbital. Their outer electronic configuration is ns1-2

Groups 13-18 constitute the p-block. Their outer electronic configuration is  ns2 np1-6

Groups 3 to 12 constitute the d-block (also called the transition elements) and are characterized by the filling of inner d-orbitals. These elements have the general outer electronic configuration (n-1)d1-10 ns0-2

Quick-Tip: Think Power Rangers.


Whoever came up with this system, must've been a fan of this show


Now look at the dismembered two rows, the lanthanoids  and actinoids, they are called the f-block or inner transition elements and their general outer electronic configuration is (n-2)f1-14(n-1)d0-1 ns2




 Locating an element


Quick Tip: Count from the nearest noble gas.

For instance, if I asked you to locate Bismuth, atomic no. 83 (and well no peeking at the periodic table)
The closest noble gas happens to be Radon, atomic no. 86, located in period 6 group 18. Therefore bismuth, atomic no. 83 is present in period 6 and group 15 (moving 3 spaces back).

Let's try Silver, atomic no. 47. (again don't sneak a peek at the periodic table). The nearest noble gas happens to be Xenon, atomic no. 54, which is located in group 18 period 5. Therefore Ag is present in  period 5, (and moving back 7 spaces) group 11.


Number of Elements in a Period

Each row (period) corresponds to the filling of a new energy level. 

In the first period, n=1 and the 1s orbital is filled. Since the 1s orbital can accomodate a total of 2 electrons, the first period also houses 2 elements (H and He)


In the second period, n=2. Thus, the 2s and 2p orbitals are filled. Therefore the 2nd period accommodates a total of 8 elements (since the 2s and 2p orbitals can together accommodate 8 electrons (6+2) )

Similarly in the 3rd period 3s and 3p orbitals are filled and it can accommodate 8 elements.

In the 4th period the 4s, 3d and 4p orbitals (refer to aufbau principle) are filled and it can thus accommodate a total of 2+10+6= 18 elements.

Similarly the 5th period corresponds to the filling of 5s 4d and 5p orbitals and thus accommodates 18 elements.

The 6th period corresponds to the filling of the 6s 4f 5d and 6p orbitals and can thus accommodate a total of 32 elements.


Similarly for the 7th period , the following orbitals are available 7s 5f 6d 7p  and it can accommodate a total of 32 elements.

Hydrogen and Helium

Hydrogen has one s-electron and can be placed in group 1 with other alkali metals. Hydrogen can also gain an electron to attain stable gas configuration and thus at times behaves like group 17 (halogens) elements. 

Helium, has the electronic configuration 1sand strictly speaking should be a part of the s-block, but since it has a completely filled valence shell its chemical properties are akin to those of other group 18 (noble gases) elements.

Nomenclature of Elements with Atomic Number Greater than 100


Ready-Reference Chart

Digit             Name                   Abbreviation

0                   nil                                  n
1                   un                                  u
2                   bi                                   b
3                   tri                                   t
4                  quad                               q
5                  pent                                p
6                  hex                                 h
7                  sept                                s
8                  oct                                 o
9                  enn                                e  



Therefore an element with atomic number 116 would be called Ununhexilium (Uuh)


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That's all folks!

Stay tuned for a follow-up post on periodic trends.

till then, The Passive Observer Out